Thermal expansion and the law of corresponding states

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, , Citation P D Pathak and N G Vasavada 1970 J. Phys. C: Solid State Phys. 3 L44 DOI 10.1088/0022-3719/3/2/002

0022-3719/3/2/L44

Abstract

The coefficients of linear expansion alpha for silver, copper and aluminium are determined by a sensitive method and compared with those of other workers. The reduced parameters alpha /( alpha )m/2 and T/Tm give a common curve for all metals. Here Tm is the melting point and ( alpha )m/2 is the value of alpha at T=1/2Tm. The curve is a straight line within the approximate limits 0.2<T/Tm<0.45 and is found to deviate considerably from linearity at higher temperatures. Assuming that the deviation is due to defects, the energies of monovacancy formation in close-packed cubic metals are estimated and are found to agree excellently with the observed values.

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10.1088/0022-3719/3/2/002