Dimerization of terminal alkynes promoted by a heterobimetallic Zr/Co complex
- The Ohio State Univ., Columbus, OH (United States)
- Brandeis Univ., Waltham, MA (United States)
Enynes are signifcant synthetic intermediates that are also found in a variety of natural products and other biologically relevant molecules. The most atom economical synthetic route to enynes is via the direct coupling of readily available terminal alkyne precursors. Towards this end, we demonstrate the formation of 1,3-enynes from terminal alkynes facilitated by a reduced ZrIV/Co-I heterobimetallic complex. An intermediate is trapped as a tBuNC adduct, revealing that bimetallic activation of the terminal C-H bond of the alkyne is an essential mechanistic step.
- Research Organization:
- The Ohio State Univ., Columbus, OH (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division
- Grant/Contract Number:
- SC0019179
- OSTI ID:
- 1596260
- Alternate ID(s):
- OSTI ID: 1597532
- Journal Information:
- Dalton Transactions, Vol. 49, Issue 8; ISSN 1477-9226
- Publisher:
- Royal Society of ChemistryCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 11 works
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