Structural diversity of alkali-metal (Li, Na, K) alkyl zincates containing bidentate aminopyrrolyl ligands: from molecular complexes to coordination polymers

Zhiqiang Guo; Yakong Wang; Wei Cao; Jianbin Chao; Xuehong Wei

doi:10.1039/C7DT00052A

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Structural diversity of alkali-metal (Li, Na, K) alkyl zincates containing bidentate aminopyrrolyl ligands: from molecular complexes to coordination polymers†

Zhiqiang Guo,

*^a Yakong Wang,^b Wei Cao,^a Jianbin Chao^a and Xuehong Wei*^ab

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* Corresponding authors

^a Scientific Instrument Center, Shanxi University, Taiyuan, P. R. China
E-mail: gzq@sxu.edu.cn, xhwei@sxu.edu.cn

^b School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan, P. R. China

Abstract

The exploration of co-complexation reactions between alkai-metal reagents and ZnEt₂ with bidentate aminopyrrolyl ligands afforded a series of alkali-metal (Li, Na, K) alkyl zincates with a variety of intriguing structures, ranging from molecular complexes to more coordination polymers. All aforementioned complexes have been characterized by X-ray crystallography, NMR, IR and UV-vis spectroscopy.

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DOI: https://doi.org/10.1039/C7DT00052A
Article type: Communication
Submitted: 06 Jan 2017
Accepted: 30 Jan 2017
First published: 30 Jan 2017

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Dalton Trans., 2017,46, 2765-2769

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Structural diversity of alkali-metal (Li, Na, K) alkyl zincates containing bidentate aminopyrrolyl ligands: from molecular complexes to coordination polymers

Z. Guo, Y. Wang, W. Cao, J. Chao and X. Wei, Dalton Trans., 2017, 46, 2765 DOI: 10.1039/C7DT00052A

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Dalton Transactions

Structural diversity of alkali-metal (Li, Na, K) alkyl zincates containing bidentate aminopyrrolyl ligands: from molecular complexes to coordination polymers†

Abstract

Supplementary files

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Structural diversity of alkali-metal (Li, Na, K) alkyl zincates containing bidentate aminopyrrolyl ligands: from molecular complexes to coordination polymers

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