Tuning the formation of reductive species of perylene-bisimide derivatives in DMF via aggregation matter

Rui Kang; Rong Miao; Yanyu Qi; Xingmao Chang; Congdi Shang; Li Wang; Yu Fang

doi:10.1039/C7CC05645A

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Tuning the formation of reductive species of perylene-bisimide derivatives in DMF via aggregation matter†

Rui Kang,^a Rong Miao,^a Yanyu Qi,^a Xingmao Chang,^b Congdi Shang,^a Li Wang^a and Yu Fang

*^a

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* Corresponding authors

^a Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education), School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, P. R. China
E-mail: yfang@snnu.edu.cn

^b Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education), Shaanxi Normal University, School of Materials Science and Engineering, Xi'an, 710119, P. R. China

Abstract

Host–guest interaction and chemical modification are found to be effective in tuning the formation of reductive species of perylene-bisimide (PBI) derivatives in DMF. Moreover, some of the PBI derivatives as synthesized produce radical anions in the solvent without the need of a base.

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Article information

DOI: https://doi.org/10.1039/C7CC05645A
Article type: Communication
Submitted: 20 Jul 2017
Accepted: 17 Aug 2017
First published: 17 Aug 2017

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Chem. Commun., 2017,53, 10018-10021

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Tuning the formation of reductive species of perylene-bisimide derivatives in DMF via aggregation matter

R. Kang, R. Miao, Y. Qi, X. Chang, C. Shang, L. Wang and Y. Fang, Chem. Commun., 2017, 53, 10018 DOI: 10.1039/C7CC05645A

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Chemical Communications

Tuning the formation of reductive species of perylene-bisimide derivatives in DMF via aggregation matter†

Abstract

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Tuning the formation of reductive species of perylene-bisimide derivatives in DMF via aggregation matter

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