Issue 29, 2014

Structural rheology of focal conic domains: a stress-quench experiment

Abstract

We study the dynamics of focal conic domain (FCD) formation in a thermotropic smectic phase under shear stress. It is known that increasing the shear stress induces a non-equilibrium phase transition from a smectic phase with FCDs (SmAI) to another smectic phase (SmAII) in which the layers are oriented. By quenching the shear stress from the SmAII phase to the SmAI phase, we find three characteristic modes in the FCD formation process. The first mode is attributed to the edge dislocation dynamics induced by climb motions. The second mode results from FCD formation. The first and second modes show slowing down close to the smectic–nematic transition temperature, implying that the dynamics are dominated by dislocation unbinding. The third mode originates from the alignment of FCDs which form oily streaks. Such an alignment occurs when the shear stress balances the line tension of the oily streaks.

Graphical abstract: Structural rheology of focal conic domains: a stress-quench experiment

Supplementary files

Article information

Article type
Paper
Submitted
19 Jan 2014
Accepted
28 Apr 2014
First published
01 May 2014

Soft Matter, 2014,10, 5289-5295

Structural rheology of focal conic domains: a stress-quench experiment

S. Fujii, S. Komura and C.-Y. D. Lu, Soft Matter, 2014, 10, 5289 DOI: 10.1039/C4SM00146J

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