Issue 90, 2014
From the journal:

Chemical Communications

Metal-free Mizoroki–Heck type reaction: a radical oxidative coupling reaction of 2-chloro-dithiane with substituted olefins†

Wenbin Du,a   Junshan Lai,a   Lixia Tian,a   Xingang Xie,b   Xuegong Sheb  and  Shouchu Tang*ab  

* Corresponding authors

a School of Pharmacy, Lanzhou University, Lanzhou 730000, P. R. China
E-mail: tangshch@lzu.edu.cn
Fax: +86-931-8915686

b State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China

Abstract

An efficient metal-free Mizoroki–Heck type reaction of di- and tri-substituted alkenes with 2-chloro-dithiane has been developed under ambient pressure of air or using a relatively low loading of BF3·Et2O. This study represents a new environmentally friendly method for the syntheses of dithianyl-substituted alkene derivatives via a radical oxidative coupling process.

Graphical abstract: Metal-free Mizoroki–Heck type reaction: a radical oxidative coupling reaction of 2-chloro-dithiane with substituted olefins

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Article information

DOI
https://doi.org/10.1039/C4CC06397J
Article type
Communication
Submitted
14 Aug 2014
Accepted
16 Sep 2014
First published
16 Sep 2014

Chem. Commun., 2014,50, 14017-14020

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Metal-free Mizoroki–Heck type reaction: a radical oxidative coupling reaction of 2-chloro-dithiane with substituted olefins

W. Du, J. Lai, L. Tian, X. Xie, X. She and S. Tang, Chem. Commun., 2014, 50, 14017 DOI: 10.1039/C4CC06397J

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