When Cu4I4 cubane meets Cu3(pyrazolate)3 triangle: dynamic interplay between two classical luminophores functioning in a reversibly thermochromic coordination polymer

Shun-Ze Zhan; Mian Li; Xiao-Ping Zhou; Jun-Hao Wang; Ju-Rong Yang; Dan Li

doi:10.1039/C1CC14303D

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When Cu₄I₄cubane meets Cu₃(pyrazolate)₃ triangle: dynamic interplay between two classical luminophores functioning in a reversibly thermochromic coordination polymer†

Shun-Ze Zhan,^a Mian Li,^a Xiao-Ping Zhou,^a Jun-Hao Wang,^a Ju-Rong Yang^a and Dan Li*^a

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* Corresponding authors

^a Department of Chemistry, Shantou University, Guangdong 515063, P. R. China
E-mail: dli@stu.edu.cn
Fax: +86 754-82902767
Tel: +86 754-82902741

Abstract

A supramolecular dual emissive system incorporating two classical copper(I)-cluster-based luminophores, namely, Cu₄I₄ and Cu₃Pz₃ (Pz = pyrazolate), is reported. The targeted luminescent coordination polymer exhibits reversible thermochromism spanning from green to orange-red.

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Article information

DOI: https://doi.org/10.1039/C1CC14303D
Article type: Communication
Submitted: 17 Jul 2011
Accepted: 16 Aug 2011
First published: 05 Sep 2011

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Chem. Commun., 2011,47, 12441-12443

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When Cu₄I₄ cubane meets Cu₃(pyrazolate)₃ triangle: dynamic interplay between two classical luminophores functioning in a reversibly thermochromic coordination polymer

S. Zhan, M. Li, X. Zhou, J. Wang, J. Yang and D. Li, Chem. Commun., 2011, 47, 12441 DOI: 10.1039/C1CC14303D

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