Issue 37, 2010
From the journal:

Chemical Communications

Palladium(ii)-catalyzed asymmetric hydrophosphination of enones: efficient access to chiral tertiary phosphines†

Yinhua Huang,a   Sumod A. Pullarkat,a   Yongxin Lia  and  Pak-Hing Leung*a  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore
E-mail: pakhing@ntu.edu.sg
Fax: +65 67911961
Tel: +65 6316 8905

Abstract

Chiral tertiary phosphines were synthesized by asymmetric hydrophosphination of aromatic enones catalyzed by an organopalladium complex with high yields and stereoselectivity. The procedure offers practical access to chiral tertiary phosphines.

Graphical abstract: Palladium(ii)-catalyzed asymmetric hydrophosphination of enones: efficient access to chiral tertiary phosphines

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Article information

DOI
https://doi.org/10.1039/C0CC00925C
Article type
Communication
Submitted
14 Apr 2010
Accepted
02 Aug 2010
First published
23 Aug 2010

Chem. Commun., 2010,46, 6950-6952

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Palladium(II)-catalyzed asymmetric hydrophosphination of enones: efficient access to chiral tertiary phosphines

Y. Huang, S. A. Pullarkat, Y. Li and P. Leung, Chem. Commun., 2010, 46, 6950 DOI: 10.1039/C0CC00925C

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