Issue 5, 2002
From the journal:

Chemical Communications

Mixed-anion complexes with a bipyrazolyl ligand. A new entry to a realm of three-dimensional five-connected coordination topologies†

Vira V. Ponomarova,a   Vasiliy V. Komarchuk,a   Ishtvan Boldog,a   Alexander N. Chernega,b   Joachim Sielerc  and  Konstantin V. Domasevitch*a  

* Corresponding authors

a Inorganic Chemistry Department, Kiev University, Volodimirska Street 64, Kiev 01033, Ukraine
E-mail: dk@anorgchemie.univ.kiev.ua

b Institute of Organic Chemistry, Murmanskaya St. 4, Kiev 253660, Ukraine

c Institut für Anorganische Chemie, Universität Leipzig, Linnéstraße 3, Germany

Abstract

Cross-linking of corrugated square grid coordination layers by anionic bridging groups generates five-connected coordination networks; the 3D topologies of mixed-anion cobalt(II) and nickel(II) complexes with a tetramethyl-substituted 4,4′-bipyrazolyl ligand are supported by μ-SO42− functions and exist as neutral or cationic five-connected arrays involving additional terminal (NCS−) or non-coordinated (NO3−, ClO4−) groups.

Graphical abstract: Mixed-anion complexes with a bipyrazolyl ligand. A new entry to a realm of three-dimensional five-connected coordination topologies

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Article information

DOI
https://doi.org/10.1039/B110599J
Article type
Communication
Submitted
19 Nov 2001
Accepted
25 Jan 2002
First published
13 Feb 2002

Chem. Commun., 2002, 436-437

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Mixed-anion complexes with a bipyrazolyl ligand. A new entry to a realm of three-dimensional five-connected coordination topologies

V. V. Ponomarova, V. V. Komarchuk, I. Boldog, A. N. Chernega, J. Sieler and K. V. Domasevitch, Chem. Commun., 2002, 436 DOI: 10.1039/B110599J

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