Issue 16, 1993

Phenolic oxidations with phenyliodonium diacetate

Abstract

Phenyliodonium diacetate (PIDA) in methanol interacts smoothly with phenols to yield p-quinones, o-quinones, 4,4-dialkoxycyclohexa-2,5-dienones or-4-alkyl-4-alkoxycyclohexa-2,5-dienones, dependant on the constitution of the phenolic substrate. The reactions proceed in mild conditions and good yields and are synthetically useful.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1993, 1891-1896

Phenolic oxidations with phenyliodonium diacetate

A. Pelter and S. M. A. Elgendy, J. Chem. Soc., Perkin Trans. 1, 1993, 1891 DOI: 10.1039/P19930001891

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