Issue 6, 1991
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Isolation of new isocyanide metabolites of Trichoderma hamatum as their (η5-pentamethylcyclopentadienyl)- or (η5-ethyltetramethylcyclopentadienyl)-di-µ-thiocyanato-rhodium complexes

R. K. Boyd,   A. J. McAlees,   A. Taylor  and  J. A. Walter  

Abstract

Many isolates of Trichoderma spp. have been shown to produce 10–20 unstable metabolites, characterized by the presence of an isocyano group, by a recently described analytical method. The purification of these metabolites can be followed by this method and in this way 4-hydroxy-8-isocyano-1-oxaspiro[4·4]cyclonon-8-en-2-one 9, 1-(2,3-epoxy-1-hydroxy-3-isocyanocyclopent-4-enyl)ethanol 13, and 1-(1,4,5-trihydroxy-2-isocyanopent-2-enyl)ethanol 11 have been isolated and characterized. The presence of an isomer of methyl 3-(1,5-dihydroxy-3-isocyanocyclopent-3-enyl)prop-2-enoate 6, previously reported has been confirmed.

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Article information

DOI
https://doi.org/10.1039/P19910001461
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1991, 1461-1465

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Isolation of new isocyanide metabolites of Trichoderma hamatum as their (η5-pentamethylcyclopentadienyl)- or (η5-ethyltetramethylcyclopentadienyl)-di-µ-thiocyanato-rhodium complexes

R. K. Boyd, A. J. McAlees, A. Taylor and J. A. Walter, J. Chem. Soc., Perkin Trans. 1, 1991, 1461 DOI: 10.1039/P19910001461

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