Issue 0, 1987
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

The chemistry of N-substituted benzotriazoles. Part 7. The isomeric composition and mechanism of interconversion of some N-(aminomethyl)benzotriazole derivatives

Alan R. Katritzky,   Konstantina Yannakopoulou,   Wojciech Kuzmierkiewicz,   Jose M. Aurrecoechea,   Gus J. Palenik,   Anna E. Koziol,   Marian Szczesniak  and  Robert Skarjune  

Abstract

A variety of N-(dialkylaminomethyl)benzotriazoles are shown by 1H and 13C n.m.r., i.r., and X-ray crystallography to exist solely in the 1-substituted form in the crystalline phase, but as an equilibrium mixture of the 1- and 2-isomers in the liquid, melt, solution and argon matrix phases. The 1- and 2-isomers equilibrate by an intermolecular mechanism as proven by cross-over experiments.

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Article information

DOI
https://doi.org/10.1039/P19870002673
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1987, 2673-2679

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The chemistry of N-substituted benzotriazoles. Part 7. The isomeric composition and mechanism of interconversion of some N-(aminomethyl)benzotriazole derivatives

A. R. Katritzky, K. Yannakopoulou, W. Kuzmierkiewicz, J. M. Aurrecoechea, G. J. Palenik, A. E. Koziol, M. Szczesniak and R. Skarjune, J. Chem. Soc., Perkin Trans. 1, 1987, 2673 DOI: 10.1039/P19870002673

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