Issue 0, 1987

The chemistry of N-substituted benzotriazoles. Part 1.1-(Chloromethyl)benzotriazole

Abstract

The N-chloromethyl group of 1-(chloromethyl)benzotriazole undergoes nucleophilic substitution by carbon, nitrogen, phosphorus, oxygen, and sulphur nucleophiles. α-Lithiation was achieved in high yield in 1-phenylthiomethyl-, 1-phenylsulphinylmethyl-, and 1-(phenylstilphonylmethyl)benzotriazoles and the lithio derivatives reacted with a variety of electrophiles. New benzotriazolium salts were prepared by quaternization of the N-3 nitrogen with methyl iodide.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1987, 781-789

The chemistry of N-substituted benzotriazoles. Part 1.1-(Chloromethyl)benzotriazole

A. R. Katritzky, S. Rachwal, K. C. Caster, F. Mahni, K. W. Law and O. Rubio, J. Chem. Soc., Perkin Trans. 1, 1987, 781 DOI: 10.1039/P19870000781

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements