2,2,2-Trifluoroethyl vinyl ketone is prepared in two steps from β-chloropropionyl fluoride and 1,1 -difluoroethylene. Condensation of this reagent with enamines or ketols leads to the formation of 2-trifluoromethylcyclohexenones.
H. Molines and C. Wakselman, J. Chem. Soc., Perkin Trans. 1, 1980, 1114 DOI: 10.1039/P19800001114
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