Issue 0, 1974
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Rearrangement reactions of bicyclic systems. Part II. Rearrangements of 1-dimethylamino-5,6,7,8-tetrahalogeno-1,4-dihydro-1,4-ethenonaphthalene derivatives and the analogous 5,6,7,8-tetrafluoro-1,4-dihydro-N-methyl-1,4-iminonaphthalene in aqueous solutions

Harry Heaney  and  Steven V. Ley  

Abstract

The title compounds rearrange to biaryl derivatives in high yields in protic media. The isolation of ketonic derivatives when aromatisation is blocked shows that the driving force for the rearrangement is not provided predominantly by the aromatisation step. Evidence for an ionic mechanism is adduced from deuterium-incorporation studies.

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Article information

DOI
https://doi.org/10.1039/P19740002698
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1974, 2698-2701

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Rearrangement reactions of bicyclic systems. Part II. Rearrangements of 1-dimethylamino-5,6,7,8-tetrahalogeno-1,4-dihydro-1,4-ethenonaphthalene derivatives and the analogous 5,6,7,8-tetrafluoro-1,4-dihydro-N-methyl-1,4-iminonaphthalene in aqueous solutions

H. Heaney and S. V. Ley, J. Chem. Soc., Perkin Trans. 1, 1974, 2698 DOI: 10.1039/P19740002698

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