Issue 0, 1972
From the journal:

Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics

Electron paramagnetic resonance of osmium-doped trichlorotris(diethylphenylphosphine)rhodium(III)

N. J. Hill  

Abstract

The paramagnetic resonance spectrum of single crystals of RhCl3(PEt2Ph)3 doped with osmium has been measured at 77 K. No hyperfine structure is resolved and the g-tensor has principal values 3.32, 1.44 and 0.32. These values are analyzed using an extended form of the standard theory for low-spin d5, including configuration interaction. The effective value of the spin-orbit coupling is 2650 ± 100 cm–1 and the orbital reduction factor is 0.80 ± 0.01. The anisotropy is compared with the molecular structure and interpreted in terms of the π-bonding properties of the ligands.

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Article information

DOI
https://doi.org/10.1039/F29726800427
Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1972,68, 427-434

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Electron paramagnetic resonance of osmium-doped trichlorotris(diethylphenylphosphine)rhodium(III)

N. J. Hill, J. Chem. Soc., Faraday Trans. 2, 1972, 68, 427 DOI: 10.1039/F29726800427

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