Issue 0, 1973
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Polymerization of methyl α-cyanoacrylate. Part 1.—Initiation by benzoyl peroxide

John C. Bevington  and  John A. L. Jemmett  

Abstract

Methyl α-cyanoacrylate has been polymerized at 60°C with dioxan as diluent, benzoyl peroxide as initiator and propane sultone to suppress anionic polymerization. Peroxide doubly labelled with carbon-14 and hydrogen-3 was used so that the relative numbers of benzoyloxy and phenyl end-groups could be determined. The monomer is comparatively unreactive towards the benzoyloxy radical so that initiation is largely by addition of phenyl radicals to molecules of monomer.

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Article information

DOI
https://doi.org/10.1039/F19736901866
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1973,69, 1866-1871

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Polymerization of methyl α-cyanoacrylate. Part 1.—Initiation by benzoyl peroxide

J. C. Bevington and J. A. L. Jemmett, J. Chem. Soc., Faraday Trans. 1, 1973, 69, 1866 DOI: 10.1039/F19736901866

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