Issue 10, 1991
From the journal:

Journal of the Chemical Society, Dalton Transactions

New bis(ferrocenecarbonyl)- and bis(ferrocenyl)-appended diazatetrathia mixed-donor macrocyclic ligands and their copper-(II) and -(I) complexes

Paul D. Beer,   Jayne E. Nation,   Sean L. W. McWhinnie,   Mary E. Harman,   Michael B. Hursthouse,   Mark I. Ogden  and  Allan H. White  

Abstract

New bis(ferrocenecarbonyl)-, bis(ferrocenyl)- and dibenzyl-appended diazatetrathia mixed-donor macrocyclic ligands L1, L2 and L3 have been prepared. Copper-(II) and -(I) complexes of these ligands have been isolated and characterised. Single-crystal X-ray structures of 7,16-bis(ferrocenemethyl)-1,4,10,13-tetrathia-7,16-diazacyclooctadecane (L2) and of its copper(I) complex [CuL2]PF6 have also been determined. Electrochemical investigations reveal the respective ferrocene–ferrocenium redox couples of ligands L1 and L2 are perturbed to more positive potentials on co-ordination of the copper(II) ion. These copper(II) complexes also exhibit quasi-reversible copper(II)–copper(I) redox couples at negative potentials (versus saturated calomel electrode).

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Article information

DOI
https://doi.org/10.1039/DT9910002485
Article type
Paper

J. Chem. Soc., Dalton Trans., 1991, 2485-2492

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New bis(ferrocenecarbonyl)- and bis(ferrocenyl)-appended diazatetrathia mixed-donor macrocyclic ligands and their copper-(II) and -(I) complexes

P. D. Beer, J. E. Nation, S. L. W. McWhinnie, M. E. Harman, M. B. Hursthouse, M. I. Ogden and A. H. White, J. Chem. Soc., Dalton Trans., 1991, 2485 DOI: 10.1039/DT9910002485

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