Issue 6, 1986
From the journal:

Journal of the Chemical Society, Dalton Transactions

Zinc carboxylate complexes: structural characterisation of some binuclear and linear trinuclear complexes

William Clegg,   Ian R. Little  and  Brian P. Straughan  

Abstract

The preparation and structural characteristics of nine air-stable binuclear zinc(II) carboxylate complexes together with 13 air-stable linear trinuclear complexes of general formula [Zn2M(carboxylate)6(base)2] where MII= Zn, Co, Ni, Cd, Mg, or Ca are reported. The crystal structure of the parent binuclear complex [Zn2(MeCH[double bond, length half m-dash]CHCO2)4(C9H7N)2](C9H7N = quinoline) has been determined. The main feature of interest is the flexibility of the tetracarboxylate framework which can bridge across a wide range of metal–metal distances (e.g. Zn ⋯ Zn 2.976 Å in this complex).

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9860001283
Article type
Paper

J. Chem. Soc., Dalton Trans., 1986, 1283-1288

Permissions

Request permissions

Zinc carboxylate complexes: structural characterisation of some binuclear and linear trinuclear complexes

W. Clegg, I. R. Little and B. P. Straughan, J. Chem. Soc., Dalton Trans., 1986, 1283 DOI: 10.1039/DT9860001283

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements