Issue 10, 1983
From the journal:

Journal of the Chemical Society, Dalton Transactions

Compartmental ligands. Part 6. Transition-metal complexes of a non-symmetric, acyclic, Schiff base derived from heptane-2,4,6-trione,1-(o-hydroxyphenyl)butane-1,3-dione, and 1,2-diaminoethane

Jean-Pierre Costes  and  David E. Fenton  

Abstract

The preparation and metal complexing properties of a non-symmetric, acyclic, Schiff base derived from heptane-2,4,6-trione, 1-(o-hydroxyphenyl)butane-1,3-dione, and 1,2-diaminoethane are described. The ligand has available dissimilar, adjacent, donor sets (N2O2 and O2O2). Both mononuclear positional isomers are found for nickel(II) and copper(II) complexes; oxovanadium(IV), dioxouranium(VI), and cobalt(II) gave only the O2O2 isomer.

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Article information

DOI
https://doi.org/10.1039/DT9830002235
Article type
Paper

J. Chem. Soc., Dalton Trans., 1983, 2235-2239

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Compartmental ligands. Part 6. Transition-metal complexes of a non-symmetric, acyclic, Schiff base derived from heptane-2,4,6-trione,1-(o-hydroxyphenyl)butane-1,3-dione, and 1,2-diaminoethane

J. Costes and D. E. Fenton, J. Chem. Soc., Dalton Trans., 1983, 2235 DOI: 10.1039/DT9830002235

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