Issue 11, 1978
From the journal:

Journal of the Chemical Society, Dalton Transactions

Studies of transition-metal oxo- and nitrido-complexes. Part 4. Reactions of osmium tetraoxide with alkynes and dienes in the presence of tertiary amines

Martin Schröder  and  William P. Griffith  

Abstract

Osmium tetraoxide (OsO4) reacts with alkynes R (R = C2H2, C2Ph2, PhC2H, or MeC2Ph) in the presence of tertiary amines L (L = pyridine or isoquinoline) to give trans-dioxo-osmium(VI) complexes [Os2O4(O4R)L4]. Reaction with dienes R (R = cyclo-octa-1,5-diene, 2,3-dimethylbuta-1,3-diene, or 4-vinylcyclohexene) in the presence of the same tertiary amines gives products [Os2O4(O4R)L4] and [OsO2(O2R)L2]. The structures of these complexes are discussed on the basis of their vibrational and 1H n.m.r. spectra. Hydrolysis of some of the complexes has been carried out and the organic products identified.

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Article information

DOI
https://doi.org/10.1039/DT9780001599
Article type
Paper

J. Chem. Soc., Dalton Trans., 1978, 1599-1602

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Studies of transition-metal oxo- and nitrido-complexes. Part 4. Reactions of osmium tetraoxide with alkynes and dienes in the presence of tertiary amines

M. Schröder and W. P. Griffith, J. Chem. Soc., Dalton Trans., 1978, 1599 DOI: 10.1039/DT9780001599

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