Issue 23, 1975
From the journal:

Journal of the Chemical Society, Dalton Transactions

Stereochemistry of copper(I) complexes. Part II. The molecular structure of the 3 : 2 reaction product between copper iodide and bis(diphenylphosphino)methane: di-µ-[bis(diphenylphosphino)methane]-µ-iodo-di-µ3-iodo-triangulo-tricopper(I)–0.5 dichloromethane

Giorgio Nardin,   Lucio Randaccio  and  Ennio Zangrando  

Abstract

The crystal structure of the title compound has been determined from three-dimensional X-ray data by the heavy-atom method and refined by anisotropic block-diagonal least-squares to R 0.056 for 3 504 independent reflections. Crystals are monoclinic, space group P21/c, with cell parameters a= 13.266(8), b= 22.667(9), c= 20.887(8)Å, β= 121.94(7)°, Z= 4. The structure consists of a triangle of distorted tetrahedral copper atoms connected by a bridge of iodine atoms and the dpm ligand. Values of Cu–P and Cu–I bond lengths and the geometry of the halogen bridges are discussed on the basis of the structural results of similar compounds.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9750002566
Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 2566-2569

Permissions

Request permissions

Stereochemistry of copper(I) complexes. Part II. The molecular structure of the 3 : 2 reaction product between copper iodide and bis(diphenylphosphino)methane: di-µ-[bis(diphenylphosphino)methane]-µ-iodo-di-µ3-iodo-triangulo-tricopper(I)–0.5 dichloromethane

G. Nardin, L. Randaccio and E. Zangrando, J. Chem. Soc., Dalton Trans., 1975, 2566 DOI: 10.1039/DT9750002566

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements