Issue 13, 1996

A telluride capped trinuclear nickel cluster [Ni33-Te)2(µ-PPh2CH2PPh2)3]n+ with four accessible redox states (n=–1, 0, 1, 2)

Abstract

The new telluride capped trinuclear nickel cluster [Ni33-Te)2(µ-dppm)3] 1 is prepared from TePPrn3, bis(cycloocta-1,5-diene)nickel(0), and dppm[bis(diphenylphosphino)methane]; results of cyclic voltammetry studies establish that 1 has a capacity for multiple electron transfer through three reversible redox couples spanning the states 1, 1, 1+, and 12+; cluster 1+ is characterized by X-ray crystallography.

Article information

Article type
Paper

Chem. Commun., 1996, 1575-1576

A telluride capped trinuclear nickel cluster [Ni33-Te)2(µ-PPh2CH2PPh2)3]n+ with four accessible redox states (n=–1, 0, 1, 2)

G. M. Ferrence, P. E. Fanwick and C. P. Kubiak, Chem. Commun., 1996, 1575 DOI: 10.1039/CC9960001575

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