Renewable energy storage via efficient reversible hydrogenation of piperidine captured CO2

Lu, Mi; Zhang, Jianghao; Yao, Yao; Sun, Junming; Wang, Yong; Lin, Hongfei

doi:10.1039/c8gc00954f

Title: Renewable energy storage via efficient reversible hydrogenation of piperidine captured CO₂

Journal Article · Wed Aug 01 00:00:00 EDT 2018 · Green Chemistry

DOI:https://doi.org/10.1039/c8gc00954f· OSTI ID:1468159

^[1]; Zhang, Jianghao ^[1]; Yao, Yao ^[1]; Sun, Junming ^[1]; Wang, Yong ^[1];

^[1]

Washington State Univ., Pullman, WA (United States). The Gene and Linda Voiland School of Chemical Engineering and Bioengineering

The storage of renewable energy is the major hurdle during the transition of fossil resources to renewables. A possible solution is to convert renewable electricity to chemical energy carriers such as hydrogen for storage. In this paper, a highly efficient formate-piperidine-adduct (FPA) based hydrogen storage system was developed. This system has shown rapid reaction kinetics of both hydrogenation of piperidine-captured CO₂ and dehydrogenation of the FPA over a carbon-supported palladium nano-catalyst under mild operating conditions. Moreover, the FPA solution based hydrogen storage system is advantageous owing to the generation of high-purity hydrogen, which is free of carbon monoxide and ammonia. In situ ATR-FTIR characterization was performed in order to provide insight into the reaction mechanisms involved. Finally, by integrating this breakthrough hydrogen storage system with renewable hydrogen and polymer electrolyte membrane fuel cells (PEMFC), in-demand cost-effective rechargeable hydrogen batteries could be realized for renewable energy storage.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; National Science Foundation (NSF)

Grant/Contract Number:: AC05-00OR22725; CBET 1748579

OSTI ID:: 1468159

Journal Information:: Green Chemistry, Vol. 20, Issue 18; ISSN 1463-9262

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 22 works

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