Enabling the sunlight driven response of thermally induced shape memory polymers by rewritable CH3NH3PbI3 perovskite coating

Yang Yang; Fusheng Ma; Zhen Li; Juan Qiao; Yen Wei; Yan Ji

doi:10.1039/C7TA01474K

Enabling the sunlight driven response of thermally induced shape memory polymers by rewritable CH₃NH₃PbI₃ perovskite coating†

Yang Yang,

^a Fusheng Ma,^b Zhen Li,

^a Juan Qiao,*^b Yen Wei*^ab and Yan Ji

*^a

Author affiliations

* Corresponding authors

^a The Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: jiyan@mail.tsinghua.edu.cn, weiyen@mail.tsinghua.edu.cn

^b Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: qjuan@mail.tsinghua.edu.cn

Abstract

Shape memory polymers (SMPs) have been widely used in our daily life (e.g. shrinkable tubes) and are expected to play more important roles in soft robotics, biomedical devices and other high-tech areas. Due to the energy shortage the world is facing now, it would be ideal to convert normal heat-driven SMPs into sunlight-responsive SMPs, so that solar energy could be converted into mechanical work. It is even more desirable to make SMPs flexibly switch between photo-responsiveness and photo-inertness. However, these objectives have not been realised so far. Here, we come up with a straightforward and low-cost method to do so by coating thermal-responsive SMPs with CH₃NH₃PbI₃ perovskite. We find that CH₃NH₃PbI₃ has excellent photo-thermal effect. As it can effectively convert solar energy into heat, the shape change of SMPs can be controlled by sunlight. The CH₃NH₃PbI₃ layer can be easily washed off with water. The coating–erasing can be repeated many times to make the SMPs photo-responsive and photo-inert alternatively. The concept introduced here will not only expand the application of many currently available thermal-responsive SMPs, but also provide a practical method to make good use of solar energy.

Article information

https://doi.org/10.1039/C7TA01474K

Article type

Communication

Submitted

17 Feb 2017

Accepted

17 Mar 2017

First published

17 Mar 2017

Download Citation

J. Mater. Chem. A, 2017,5, 7285-7290

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Enabling the sunlight driven response of thermally induced shape memory polymers by rewritable CH₃NH₃PbI₃ perovskite coating

Y. Yang, F. Ma, Z. Li, J. Qiao, Y. Wei and Y. Ji, J. Mater. Chem. A, 2017, 5, 7285 DOI: 10.1039/C7TA01474K

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Journal of Materials Chemistry A