Issue 65, 2016
From the journal:

RSC Advances

Synthesis of 3-phosphinoylquinolines via a phosphinoylation–cyclization–aromatization process mediated by tert-butyl hydroperoxide†

Pengbo Zhang,a   Liangliang Zhang,a   Yuzhen Gao,a   Guo Tang*a  and  Yufen Zhaoa  

* Corresponding authors

a Department of Chemistry, College of Chemistry and Chemical Engineering, The Key Laboratory for Chemical Biology of Fujian Province, Xiamen University, Xiamen, China
E-mail: t12g21@xmu.edu.cn
Fax: +86-592-2185780

Abstract

The first metal-free phosphinoylation–cyclization–aromatization method has been developed. The present methodology produces a series of substituted 3-phosphinoylquinolines in moderate to good yields from N-propargylanilines and H-phosphine oxides mediated by tert-butyl hydroperoxide.

Graphical abstract: Synthesis of 3-phosphinoylquinolines via a phosphinoylation–cyclization–aromatization process mediated by tert-butyl hydroperoxide

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Article information

DOI
https://doi.org/10.1039/C6RA11426A
Article type
Communication
Submitted
03 May 2016
Accepted
19 Jun 2016
First published
20 Jun 2016

RSC Adv., 2016,6, 60922-60925

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Synthesis of 3-phosphinoylquinolines via a phosphinoylation–cyclization–aromatization process mediated by tert-butyl hydroperoxide

P. Zhang, L. Zhang, Y. Gao, G. Tang and Y. Zhao, RSC Adv., 2016, 6, 60922 DOI: 10.1039/C6RA11426A

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