Palladium salt and functional reduced graphene oxide complex: in situ preparation of a generally applicable catalyst for C–C coupling reactions

Sheng Wang; Donghua Hu; Wenwen Hua; Jiangjiang Gu; Qiuhong Zhang; Xudong Jia; Kai Xi

doi:10.1039/C5RA10585D

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Palladium salt and functional reduced graphene oxide complex: in situ preparation of a generally applicable catalyst for C–C coupling reactions†

Sheng Wang,^a Donghua Hu,^b Wenwen Hua,^b Jiangjiang Gu,^a Qiuhong Zhang,^a Xudong Jia*^a and Kai Xi*^b

Author affiliations

* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, Department of Polymer Science & Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P. R. China
E-mail: jiaxd@nju.edu.cn
Fax: +86-25-83621337

^b Department of Polymer Science & Engineering, Nanjing University, Nanjing 210093, P. R. China
E-mail: xikai@nju.edu.cn
Fax: +86-25-83686197

Abstract

A novel Pd catalyst was designed by affording Pd²⁺ salt on the surface of functional reduced graphene oxide (FRGO), providing a new cheap and stable in situ prepared palladium catalyst for C–C coupling reactions, including the Heck reaction, Suzuki reaction, C–H bond functionalization reactions of thiophenes, and terminal alkyne C–H activation and homocoupling.

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Article information

DOI: https://doi.org/10.1039/C5RA10585D
Article type: Paper
Submitted: 22 Apr 2015
Accepted: 12 Jun 2015
First published: 12 Jun 2015

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RSC Adv., 2015,5, 53935-53939

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Palladium salt and functional reduced graphene oxide complex: in situ preparation of a generally applicable catalyst for C–C coupling reactions

S. Wang, D. Hu, W. Hua, J. Gu, Q. Zhang, X. Jia and K. Xi, RSC Adv., 2015, 5, 53935 DOI: 10.1039/C5RA10585D

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Palladium salt and functional reduced graphene oxide complex: in situ preparation of a generally applicable catalyst for C–C coupling reactions†

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Palladium salt and functional reduced graphene oxide complex: in situ preparation of a generally applicable catalyst for C–C coupling reactions

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