Issue 45, 2013
From the journal:

Journal of Materials Chemistry C

High-performance electron-transporting hybrid rylenes with low threshold voltage†

Xiangguang Li,ab   Chengyi Xiao,ab   Wei Jiang*a  and  Zhaohui Wang*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: jiangwei@iccas.ac.cn, wangzhaohui@iccas.ac.cn
Fax: +86-10-62653617
Tel: +86-10-62653617

b University of Chinese Academy of Sciences, Beijing, China
Fax: +86-10-62653617
Tel: +86-10-62653617

Abstract

We present here a new family of hybrid rylene arrays (3a–d) by the combination of Stille coupling and C–H transformation via a facile one-pot synthesis. The π-expanded rylene diimides exhibit broadened and intensive optical absorption accompanied by higher electron affinity. The linear alkyl chain substituted NDI-diPDI-NDI (3b) revealed its electron transporting characteristics with good air stability and low threshold voltage.

Graphical abstract: High-performance electron-transporting hybrid rylenes with low threshold voltage

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Article information

DOI
https://doi.org/10.1039/C3TC31644K
Article type
Paper
Submitted
20 Aug 2013
Accepted
23 Sep 2013
First published
23 Sep 2013

J. Mater. Chem. C, 2013,1, 7513-7518

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High-performance electron-transporting hybrid rylenes with low threshold voltage

X. Li, C. Xiao, W. Jiang and Z. Wang, J. Mater. Chem. C, 2013, 1, 7513 DOI: 10.1039/C3TC31644K

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