Different stereocontrol is observed in the formation of spiro skeletons via a carbonyl ene reaction and a palladium-catalysed carbonyl allylation, and a formal synthesis of (+)-perhydrohistrionicotoxin is accomplished.
N. Maezaki, H. Fukuyama, S. Yagi, T. Tanaka and C. Iwata, J. Chem. Soc., Chem. Commun., 1994, 1835 DOI: 10.1039/C39940001835
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