Issue 24, 1993

Synthesis of mono- and di-cationic phosphorus–zirconium species

Abstract

Synthesis and characterisation of zirconium containing phosphonium salts are reported, including the X-ray molecular structure determination of [{(Pri2)N}2P(Me)(CH2)2C([double bond, length half m-dash]NBut)Zr(η-C5H5)2OSO2CF3]OSO2CF35a; lability of the zirconium–oxygen covalent bond in 5a allows the preparation of the phosphorus–zirconium dicationic species 6a[{(Pri2)N}2P(Me)(CH2)2C([double bond, length half m-dash]NBut)Zr(η-C5H5)][(OSO2CF3)]2.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1866-1867

Synthesis of mono- and di-cationic phosphorus–zirconium species

F. Boutonnet, M. Zablocka, A. Igau, J. Majoral, B. Raynaud and J. Jaud, J. Chem. Soc., Chem. Commun., 1993, 1866 DOI: 10.1039/C39930001866

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