Issue 7, 1993

Catalytic conversion of (β,γ-unsaturated esters, amides and nitriles into γ-alkoxy or γ-hydroxy α,β-unsaturated derivatives induced by persulfate anion oxidation of diphenyl diselenide

Abstract

The reaction of β,γ-unsaturated esters, amides and nitriles with catalytic amounts of diphenyl diselenide and an excess of ammonium persulfate in alcohols or in water affords γ-alkoxy or γ-hydroxy α,β- unsaturated derivatives, respectively, in good yields.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 637-639

Catalytic conversion of (β,γ-unsaturated esters, amides and nitriles into γ-alkoxy or γ-hydroxy α,β-unsaturated derivatives induced by persulfate anion oxidation of diphenyl diselenide

M. Tiecco, L. Testaferri, M. Tingoli, L. Bagnoli and C. Santi, J. Chem. Soc., Chem. Commun., 1993, 637 DOI: 10.1039/C39930000637

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