Synthesis of N,N′-phenyleneporphyrines. Models for cytochrome P-450–1-aminobenzotriazole inactivation products
Abstract
N,N′-Phenyleneporphyrins were prepared either by oxidative cyclisation of cobalt(II)-N-phenylporphyrins or by direct interaction of a cobalt(III)-porphyrin and 1-aminobenzotriazole in the presence of dioxygen.