Issue 24, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

Unusual group 14 metal thiolates and sulphides derived from tris(trimethylsilyl)methanethiol; X-ray structures of [Pb(NR2)(µ-SCR3)]2 and cis-[Ge(CH2Ph)(NR2)(µ-S)]2, (R = SiMe3)

Peter B. Hitchcock,   Hatam A. Jasim,   Rosemary E. Kelly  and  Michael F. Lappert  

Abstract

The reaction of tris(trimethylsilyl)menthanethiol, HSCR3(R = SiMe3), with a group 14†; metal(II) bis(trimethylsilyl)amide, M(NR2)2(M = Ge or Pb), gives unexpected products: cis- and trans-[Ge(CH2Ph)(NR2)(µ-S)]2[a rare example of a group 14 cyclodi(metalthiane), {MXX(µ-S)}2, by refluxing in PhMe]; [Pb(SCR3)(µ-SCR3)]2(the new ligand SCR3 evidently can function in both a terminal and a bridging fashion); and [Pb(NR2)(µ-SCR3)]2, the first simple prochiral group 14 metal(II) complex.

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Article information

DOI
https://doi.org/10.1039/C39850001776
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1776-1778

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Unusual group 14 metal thiolates and sulphides derived from tris(trimethylsilyl)methanethiol; X-ray structures of [Pb(NR2)(µ-SCR3)]2 and cis-[Ge(CH2Ph)(NR2)(µ-S)]2, (R = SiMe3)

P. B. Hitchcock, H. A. Jasim, R. E. Kelly and M. F. Lappert, J. Chem. Soc., Chem. Commun., 1985, 1776 DOI: 10.1039/C39850001776

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