The presence of an amino substituent at the 2-vinyl position in substituted allyl vinyl ethers facilitates low-temperature rearrangements through [3,3]- or [1,3]-sigmatropic shifts, which lead to the aminoaldehydes (3) and (5), respectively.
J. Barluenga, F. Aznar, R. Liz and M. Bayod, J. Chem. Soc., Chem. Commun., 1984, 1427 DOI: 10.1039/C39840001427
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