The Diels–Alder reaction of furan and phenylsulphonylpropadiene gives predominantly the 7-oxabicyclo[2.2.1]heptane (1), whose hydrogenation products (3) and (4)provide a simple entry to the synthesis of substituted cyclohexenols.
A. J. Guildford and R. W. Turner, J. Chem. Soc., Chem. Commun., 1983, 466 DOI: 10.1039/C39830000466
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