Hydromagnesiation of 3-trimethyksilylprop-2-yn-1-ol affords the alkenylmagnesium halide (3) exclusively, which is valuable as a precursor of various (E)-3-trimethysilylalk-2-en-1-ols.
F. Sato, H. Watanabe, Y. Tanaka and M. Sato, J. Chem. Soc., Chem. Commun., 1982, 1126 DOI: 10.1039/C39820001126
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