Issue 9, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

Asymmetric hydroformylation using homogeneous and polymer-bound chiral platinum catalysts

Charles U. Pittman, Jr.,   Yasuziro Kawabata  and  Larry I. Flowers  

Abstract

The PtCl2–SnCl2 complexes of the chiral ligands (4R, 5R)-2,2-dimethyl-4,5-bis (diphenylphosphinomethyl)-1,3-dioxolan [(–)-DIOP] and its bis(dibenzophosphole) analogue (–)-DBP-DIOP were employed as catalysts in homogeneous asymmetric hydroformylations of styrene, and high optical yields (ca. 94%) were obtained, the polymer-bound (–)-DIOP–PtCl2–SnCl2 giving optical yields of 25–30%; the rates, branched:normal isomer ratios, and optical yields were dependent on the gas pressure, H2:CO ratio, and temperature.

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Article information

DOI
https://doi.org/10.1039/C39820000473
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 473-474

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Asymmetric hydroformylation using homogeneous and polymer-bound chiral platinum catalysts

C. U. Pittman, Y. Kawabata and L. I. Flowers, J. Chem. Soc., Chem. Commun., 1982, 473 DOI: 10.1039/C39820000473

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