Issue 19, 1978

Convenient synthesis of allenyl sulphides; application to the synthesis of αβ-unsaturated ketones

Abstract

P2S5 in methylene chloride containing pyridine reduces allenyl phenyl sulphoxides to sulphides; the difficult hydrolysis of the latter is eased by the introduction of a methoxy group into the benzene ring and this method then becomes a practicable synthesis of αβ-unsaturated ketones.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 822-824

Convenient synthesis of allenyl sulphides; application to the synthesis of αβ-unsaturated ketones

R. C. Cookson and P. J. Parsons, J. Chem. Soc., Chem. Commun., 1978, 822 DOI: 10.1039/C39780000822

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