Issue 13, 1978

Unusual conditions for cine-substitution in the pyrrole ring: isolation of a pyrroline as an intermediate

Abstract

1-Methyl-3,4-dinitropyrrole (1) reacts with methoxide in methanol to yield a 2-pyrroline (2); the regiospecific acid-promoted decomposition of (2) yields 2-methoxy-1-methyl-4-nitropyrrole (3) formally the product of cine-substitution of (1).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 564-565

Unusual conditions for cine-substitution in the pyrrole ring: isolation of a pyrroline as an intermediate

P. Mencarelli and F. Stegel, J. Chem. Soc., Chem. Commun., 1978, 564 DOI: 10.1039/C39780000564

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