SCHEDULED MAINTENANCE
The in situ acylation of nucleophiles generated cathodically from canthaxanthin (1) provides a novel and convenient route to the retro-diacetate (2) and the corresponding retro-monoacetate (3); these are hydrolysed to respectively, 5,5′-dihydrocanthaxanthin (8) and 7,7′-dihydrocanthaxanthin (4).
E. A. H. Hall, G. P. Moss, J. H. P. Utley and B. C. L. Weedon, J. Chem. Soc., Chem. Commun., 1976, 586 DOI: 10.1039/C39760000586
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