The photoelectron spectrum of phenylpentamethyldisilane, a substituted benzene in which the σ-electrons of the substituent are more easily ionized than the benzene π-electrons, has been determined; the highest occupied MO is assigned to a linear combination of π(C6H5) and σ(SiSi) orbitals, resulting from σ–π mixing.
C. G. Pitt and H. Bock, J. Chem. Soc., Chem. Commun., 1972, 28 DOI: 10.1039/C39720000028
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