Issue 11, 1971

Complexes containing cobalt–silicon metal–metal bonds

Abstract

The complexes (Ph3P)3CoH2(SiR3)(R [double bond, length half m-dash] F, OEt) are formed by an oxidative-elimination reaction between R3SiH and (Ph3P)3Co(N2)H; the reaction is reversible when R [double bond, length half m-dash] OEt, and this complex function as an efficient catalyst for O-silylation and hydrosilylation reactions.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 524-525

Complexes containing cobalt–silicon metal–metal bonds

N. J. Archer, R. N. Haszeldine and R. V. Parish, J. Chem. Soc. D, 1971, 524 DOI: 10.1039/C29710000524

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