Issue 11, 2011
From the journal:

New Journal of Chemistry

Silica-supported single-site catalysts: to be or not to be? A conjecture on silica surfaces†

David Gajana  and  Christophe Copéret*a  

* Corresponding authors

a ETH Zürich, Department of Chemistry, Wolfgang Pauli Strasse 10, CH-8093 Z, Switzerland
E-mail: ccoperet@inorg.chem.ethz.ch
Fax: +41-44-633-13-25
Tel: +41-44-633-93-94

Abstract

Well-defined surface species can be generated on silica, but as expected for an amorphous support their environment is heterogeneous thus preventing the formation of true single-site species even for monopodal species, and it is particularly evident for multipodal species, ([triple bond, length as m-dash]SiO)xM, x > 1.

Graphical abstract: Silica-supported single-site catalysts: to be or not to be? A conjecture on silica surfaces

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Article information

DOI
https://doi.org/10.1039/C1NJ20506D
Article type
Focus
Submitted
10 Jun 2011
Accepted
05 Aug 2011
First published
24 Aug 2011

New J. Chem., 2011,35, 2403-2408

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Silica-supported single-site catalysts: to be or not to be? A conjecture on silica surfaces

D. Gajan and C. Copéret, New J. Chem., 2011, 35, 2403 DOI: 10.1039/C1NJ20506D

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