Issue 36, 2006

A single-bonded cationic terminal borylene complex

Abstract

The cationic terminal borylene complex [(η5-C5H5)(CO)2FeB(η5-C5Me5)][AlCl4] has been isolated from the reaction of [(η5-C5H5)(CO)2FeB(Cl)(η1-C5Me5)] with AlCl3 and on the basis of X-ray crystallographic data, spectroscopic data and a DFT calculation it is concluded that the B→Fe bond order is one.

Graphical abstract: A single-bonded cationic terminal borylene complex

Supplementary files

Article information

Article type
Communication
Submitted
07 Jul 2006
Accepted
22 Jul 2006
First published
08 Aug 2006

Chem. Commun., 2006, 3786-3787

A single-bonded cationic terminal borylene complex

D. Vidovic, M. Findlater, G. Reeske and A. H. Cowley, Chem. Commun., 2006, 3786 DOI: 10.1039/B609475A

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