Issue 14, 2006
From the journal:

Chemical Communications

The Al(i) bisimidinate Al(DDP) as a metalloid NHC type ligand for Pd(0) complexes and clusters

Andreas Kempter,a   Christian Gemela  and  Roland A. Fischer*a  

* Corresponding authors

a Anorganische Chemie II, Organometallics and Materials Chemistry, Ruhr-Universität Bochum, Universitätsstraße 150, 44780 Bochum, Germany
E-mail: Roland.Fischer@ruhr-uni-bochum.de
Fax: +49 234 321 4174
Tel: +49 234 321 4174

Abstract

Two clusters with a Pd2 core and Al(DDP) (DDP = 2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene) as a bridging ligand have been synthesized and characterized by single crystal structural analysis; the results suggest a strong similarity of the coordination properties of NHC's and the group 13 analogue Al(DDP).

Graphical abstract: The Al(i) bisimidinate Al(DDP) as a metalloid NHC type ligand for Pd(0) complexes and clusters

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Article information

DOI
https://doi.org/10.1039/B518065A
Article type
Communication
Submitted
20 Dec 2005
Accepted
16 Feb 2006
First published
02 Mar 2006

Chem. Commun., 2006, 1551-1553

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The Al(I) bisimidinate Al(DDP) as a metalloid NHC type ligand for Pd(0) complexes and clusters

A. Kempter, C. Gemel and R. A. Fischer, Chem. Commun., 2006, 1551 DOI: 10.1039/B518065A

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