Issue 30, 2005
From the journal:

Chemical Communications

Non-steady-state living polymerization: a new route to control cationic ring-opening polymerization (CROP) of oxetanevia an activation chain end (ACE) mechanism at ambient temperature

Hassen Bouchékif,*a   Marcia I. Philbin,b   Eamon Colcloughb  and  Allan J. Amass*a  

* Corresponding authors

a School of Chemical Engineering & Applied Chemistry (CEAC), Aston University, Birmingham, UK
E-mail: hbouchekif@yahoo.fr, a.j.amass@aston.ac.uk
Fax: (44)0121-3594094
Tel: (44)0121-243373

b QinetiQ (DERA) Fort Halstead, Sevenoaks, Kent, UK

Abstract

Well-defined polyoxetane with low polydispersivity has been synthesized via a novel living polymerisation process using 3-phenoxypropyl 1,4-dioxanium hexafluoroantimonate (3-PPD) as a model of a living “monomeric polyoxetane” initiator, in 1,4-dioxane at 35°C.

Graphical abstract: Non-steady-state living polymerization: a new route to control cationic ring-opening polymerization (CROP) of oxetane via an activation chain end (ACE) mechanism at ambient temperature

About
Cited by
Related
Download options Please wait...

Supplementary files

Additions and corrections

Article information

DOI
https://doi.org/10.1039/B417076H
Article type
Communication
Submitted
10 Nov 2004
Accepted
26 Apr 2005
First published
15 Jun 2005

Chem. Commun., 2005, 3870-3872

Permissions

Request permissions

Non-steady-state living polymerization: a new route to control cationic ring-opening polymerization (CROP) of oxetane via an activation chain end (ACE) mechanism at ambient temperature

H. Bouchékif, M. I. Philbin, E. Colclough and A. J. Amass, Chem. Commun., 2005, 3870 DOI: 10.1039/B417076H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements