Issue 11, 2004
From the journal:

Chemical Communications

Photocontrol of electron transfer from Zn-porphyrin to an axially bound stilbazole–pyromellitic diimide conjugate†

Joe Otsuki,*a   Atsushi Suka,a   Katsutoshi Yamazaki,a   Hideyuki Abe,a   Yasuyuki Arakib  and  Osamu Itob  

* Corresponding authors

a College of Science and Technology, Nihon University, Kanda Surugadai, Chiyoda-ku, Tokyo 101-8308, Japan
E-mail: otsuki@chem.cst.nihon-u.ac.jp
Fax: +81 3 3259 0817
Tel: +81 3 3259 0817

b Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Katahira, Aoba-ku, Sendai 980-8577, Japan

Abstract

A photochromic stilbazole unit has been incorporated into the bridge in a donor–bridge–acceptor scaffold constructed via a coordination interaction, wherein an efficient electron transfer occurs for the cis isomer of the bridge whereas no electron transfer is detected for the trans isomer.

Graphical abstract: Photocontrol of electron transfer from Zn-porphyrin to an axially bound stilbazole–pyromellitic diimide conjugate

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Article information

DOI
https://doi.org/10.1039/B403991B
Article type
Communication
Submitted
16 Mar 2004
Accepted
06 Apr 2004
First published
05 May 2004

Chem. Commun., 2004, 1290-1291

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Photocontrol of electron transfer from Zn-porphyrin to an axially bound stilbazole–pyromellitic diimide conjugate

J. Otsuki, A. Suka, K. Yamazaki, H. Abe, Y. Araki and O. Ito, Chem. Commun., 2004, 1290 DOI: 10.1039/B403991B

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