Issue 7, 2004

A centred, elongated ‘ferric tetrahedron’ with an S = 15/2 spin ground state

Abstract

The reaction of anhydrous FeCl3 with 1H-benzotriazole-1-methanol (Bta-CH2OH) in MeOH produces the pentanuclear complex [Fe5O2(OMe)2(Bta)4(BtaH)(MeOH)5Cl5], containing a distorted tetrahedron of four Fe ions centred on a fifth. The central Fe is antiferromagnetically coupled to the peripheral Fe ions resulting in an S = 15/2 spin ground state.

Graphical abstract: A centred, elongated ‘ferric tetrahedron’ with an S = 15/2 spin ground state

Supplementary files

Article information

Article type
Communication
Submitted
22 Jan 2004
Accepted
27 Feb 2004
First published
04 Mar 2004

Dalton Trans., 2004, 975-976

A centred, elongated ‘ferric tetrahedron’ with an S = 15/2 spin ground state

J. Tabernor, L. F. Jones, S. L. Heath, C. Muryn, G. Aromí, J. Ribas, E. K. Brechin and D. Collison, Dalton Trans., 2004, 975 DOI: 10.1039/B403041A

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