Issue 9, 2004
From the journal:

Physical Chemistry Chemical Physics

Liquid–liquid phase equilibria in nitrobenzene–hexane critical mixture under negative pressure†

A. Drozd-Rzoska,a   S. J. Rzoskaa  and  A. R. Imre*b  

* Corresponding authors

a Institute of Physics, Silesian University, ul. Uniwersytecka 4, Katowice, Poland
E-mail: rzoska@us.edu.pl

b KFKI Atomic Energy Research Institute, POB 49, Budapest, Hungary
E-mail: imre@sunserv.kfki.hu

Abstract

A new method has been presented in this paper on the determination of the liquid–liquid critical locus of a binary liquid mixture (nitrobenzene/n-hexane) under negative pressure, using experimental data obtained from measurements performed on positive pressures. The method is based on the pre-transitional anomaly of the dielectric permittivity and enables us to determine the liquid–liquid locus down to −20 MPa without actually going below P = 0.

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Article information

DOI
https://doi.org/10.1039/B315412B
Article type
Paper
Submitted
27 Nov 2003
Accepted
02 Feb 2004
First published
01 Mar 2004

Phys. Chem. Chem. Phys., 2004,6, 2291-2294

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Liquid–liquid phase equilibria in nitrobenzene–hexane critical mixture under negative pressure

A. Drozd-Rzoska, S. J. Rzoska and A. R. Imre, Phys. Chem. Chem. Phys., 2004, 6, 2291 DOI: 10.1039/B315412B

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