Issue 6, 2003

Double carbonylation and beyond: systems at work and their organometallic models

Abstract

A quarter of a century after its (serendipitous) discovery, the catalytic sequential chaining of two carbon monoxides into an organic substrate (the so called double carbonylation reaction), is still not well understood. After a review of the most important experimental results, this Perspective proposes a critical survey of the main organometallic models and outlines some rather neglected tracks. Finally, the issue of the chaining of more than two carbon monoxides is also addressed.

Graphical abstract: Double carbonylation and beyond: systems at work and their organometallic models

Article information

Article type
Perspective
Submitted
17 Sep 2002
Accepted
17 Dec 2002
First published
26 Feb 2003

Dalton Trans., 2003, 1041-1052

Double carbonylation and beyond: systems at work and their organometallic models

H. des Abbayes and J. Salaün, Dalton Trans., 2003, 1041 DOI: 10.1039/B209103H

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